alpha anomers
α-异头物
beta anomers
β-异头物
anomers interconvert
异头物相互转化
anomers differ
异头物不同
anomers are stereoisomers that differ at the anomeric carbon atom in cyclic sugars.
差向异构体是在环状糖中差向碳原子处不同的立体异构体。
the alpha and beta anomers interconvert through the open-chain form in aqueous solution.
α和β差向异构体通过开链形式在 aqueous 溶液中相互转化。
anomeric effect significantly influences the relative stability of anomers in pyranose rings.
差向效应显著影响吡喃糖环中差向异构体的相对稳定性。
glycosidic bonds form when the anomeric carbon of one sugar reacts with a hydroxyl group of another.
当一个糖的差向碳原子与另一个糖的羟基反应时形成糖苷键。
the anomeric configuration determines whether a glycoside is an alpha or beta anomer.
差向构型决定糖苷是α还是β差向异构体。
mutarotation is the process by which anomers reach equilibrium through ring opening and closing.
变旋光是差向异构体通过开环和闭环达到平衡的过程。
nmr spectroscopy provides a reliable method for distinguishing anomers based on their chemical shifts.
核磁共振光谱根据化学位移提供了区分差向异构体的可靠方法。
the anomeric ratio at equilibrium varies depending on the specific sugar and solvent conditions.
平衡时的差向异构体比例因具体糖和溶剂条件而异。
enzymes such as glycosidases are highly specific for cleaving particular anomers of glycosidic bonds.
糖苷酶等酶对切割糖苷键的特定差向异构体具有高度特异性。
anomeric carbon undergoes nucleophilic attack during the formation of glycosidic linkages.
差向碳原子在糖苷键形成过程中受到亲核攻击。
the sweetness perception of sugars can be affected by the proportion of different anomers present.
糖的甜度感知会受到不同差向异构体比例的影响。
acid catalysis promotes anomerization by facilitating the ring-opening step of sugars.
酸催化通过促进糖的开环步骤来促进差向异构化。
alpha anomers
α-异头物
beta anomers
β-异头物
anomers interconvert
异头物相互转化
anomers differ
异头物不同
anomers are stereoisomers that differ at the anomeric carbon atom in cyclic sugars.
差向异构体是在环状糖中差向碳原子处不同的立体异构体。
the alpha and beta anomers interconvert through the open-chain form in aqueous solution.
α和β差向异构体通过开链形式在 aqueous 溶液中相互转化。
anomeric effect significantly influences the relative stability of anomers in pyranose rings.
差向效应显著影响吡喃糖环中差向异构体的相对稳定性。
glycosidic bonds form when the anomeric carbon of one sugar reacts with a hydroxyl group of another.
当一个糖的差向碳原子与另一个糖的羟基反应时形成糖苷键。
the anomeric configuration determines whether a glycoside is an alpha or beta anomer.
差向构型决定糖苷是α还是β差向异构体。
mutarotation is the process by which anomers reach equilibrium through ring opening and closing.
变旋光是差向异构体通过开环和闭环达到平衡的过程。
nmr spectroscopy provides a reliable method for distinguishing anomers based on their chemical shifts.
核磁共振光谱根据化学位移提供了区分差向异构体的可靠方法。
the anomeric ratio at equilibrium varies depending on the specific sugar and solvent conditions.
平衡时的差向异构体比例因具体糖和溶剂条件而异。
enzymes such as glycosidases are highly specific for cleaving particular anomers of glycosidic bonds.
糖苷酶等酶对切割糖苷键的特定差向异构体具有高度特异性。
anomeric carbon undergoes nucleophilic attack during the formation of glycosidic linkages.
差向碳原子在糖苷键形成过程中受到亲核攻击。
the sweetness perception of sugars can be affected by the proportion of different anomers present.
糖的甜度感知会受到不同差向异构体比例的影响。
acid catalysis promotes anomerization by facilitating the ring-opening step of sugars.
酸催化通过促进糖的开环步骤来促进差向异构化。
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